SAFETY DATA SHEETS
According to the UN GHS revision 10
SECTION 1: Identification
1.1 GHS Product identifier
| Product name |
Copper |
|---|
1.2 Other means of identification
| Product number |
- |
|---|---|
| Other names |
cda102;cda110;cda101 |
1.3 Recommended use of the chemical and restrictions on use
| Identified uses |
Industrial and scientific research use. |
|---|---|
| Uses advised against |
no data available |
1.4 Supplier's details
| Company |
chemicalbook |
|---|---|
| Address |
507, building 1, Huihuang international, Shangdi 10th Street, Haidian District, Beijing |
| Telephone |
+86-10-69703845 |
1.5 Emergency phone number
| Emergency phone number |
+86-13121892008 |
|---|---|
| Service hours |
Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). |
SECTION 2: Hazard identification
2.1 Classification of the substance or mixture
Not classified.
2.2 GHS label elements, including precautionary statements
| Pictogram(s) | No symbol. |
|---|---|
| Signal word |
No signal word |
| Hazard statement(s) |
none |
| Precautionary statement(s) | |
| Prevention |
none |
| Response |
none |
| Storage |
none |
| Disposal |
none |
2.3 Other hazards which do not result in classification
no data available
SECTION 3: Composition/information on ingredients
3.1 Substances
| Chemical name | Common names and synonyms | CAS number | EC number | Concentration |
|---|---|---|---|---|
| Copper | Copper | 7440-50-8 | 231-159-6 | 100% |
SECTION 4: First-aid measures
4.1 Description of necessary first-aid measures
If inhaled
Fresh air, rest. Refer for medical attention.
Following skin contact
Remove contaminated clothes. Rinse and then wash skin with water and soap.
Following eye contact
Rinse with plenty of water (remove contact lenses if easily possible).
Following ingestion
Rinse mouth. Refer for medical attention .
4.2 Most important symptoms/effects, acute and delayed
Exposure Routes: inhalation, ingestion, skin and/or eye contact Symptoms: Irritation eyes, respiratory system; cough, dyspnea (breathing difficulty), wheezing; [potential occupational carcinogen] Target Organs: Eyes, skin, respiratory system, liver, kidneys (increase(d) risk with Wilson's disease) (NIOSH, 2016)
4.3 Indication of immediate medical attention and special treatment needed, if necessary
Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for shock and treat if necessary . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal . Copper and related compounds
SECTION 5: Fire-fighting measures
5.1 Suitable extinguishing media
Use special powder, dry sand. NO other agents. Water may be ineffective.
5.2 Specific hazards arising from the chemical
Combustible. Finely dispersed particles form explosive mixtures in air.
5.3 Special protective actions for fire-fighters
Use special powder, dry sand. NO other agents. Water may be ineffective.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. Carefully collect remainder. Then store and dispose of according to local regulations.
6.2 Environmental precautions
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. Carefully collect remainder. Then store and dispose of according to local regulations.
6.3 Methods and materials for containment and cleaning up
1. ventilate area of release. 2. collect spilled material in the most convenient and safe manner for reclamation, or for disposal in a secure sanitary landfill. liq containing copper should be absorbed in vermiculite, dry sand, earth, or a similar material. copper dusts & mists
SECTION 7: Handling and storage
7.1 Precautions for safe handling
NO open flames. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
7.2 Conditions for safe storage, including any incompatibilities
See Chemical Dangers.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational Exposure limit values
TLV: (fume, as Cu): 0.2 mg/m3, as TWA.TLV: (dust and mists, as Cu): 1 mg/m3, as TWA.MAK: (respirable fraction): 0.01 mg/m3; peak limitation category: II(2); pregnancy risk group: C
Biological limit values
no data available
8.2 Appropriate engineering controls
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
8.3 Individual protection measures, such as personal protective equipment (PPE)
Eye/face protection
Wear safety goggles.
Skin protection
Protective gloves.
Respiratory protection
Use local exhaust or breathing protection.
Thermal hazards
no data available
SECTION 9: Physical and chemical properties and safety characteristics
| Physical state |
Solid. Powder. |
|---|---|
| Colour |
Copper colour. |
| Odour |
Odorless /Copper dusts and mists/ |
| Melting point/freezing point |
Ca. 1 059 °C. Remarks:Mass increase, indicative of oxidation starts at 200°C. |
| Boiling point or initial boiling point and boiling range |
2567°C(lit.) |
| Flammability |
Noncombustible Solid in bulk form, but powdered form may ignite. |
| Lower and upper explosion limit/flammability limit |
no data available |
| Flash point |
18°C |
| Auto-ignition temperature |
> 1 059 °C. Remarks:No self-ignition observed up to the melting point. |
| Decomposition temperature |
no data available |
| pH |
no data available |
| Kinematic viscosity |
no data available |
| Solubility |
Insoluble (NIOSH, 2016) |
| Partition coefficient n-octanol/water |
-0.57 (calculated) |
| Vapour pressure |
7.5 nanopascal. Temperature:20 °C. Remarks:The calculated vapour pressure values are extrapolated with the Antoine constants from the regression of the data below 140°C (data points 1-8) for temperature 20,25 and 50 °C.;18 nanopascal. Temperature:25 °C. Remarks:The calculated vapour pressure values are extrapolated with the Antoine constants from the regression of the data below 140°C (data points 1-8) for temperature 20,25 and 50 °C.;840 nanopascal. Temperature:50 °C. Remarks:The calculated vapour pressure values are extrapolated with the Antoine constants from the regression of the data below 140°C (data points 1-8) for temperature 20,25 and 50 °C. |
| Density and/or relative density |
Ca. 8.78 g/cm3. Temperature:20 °C. |
| Relative vapour density |
no data available |
| Particle characteristics |
no data available |
SECTION 10: Stability and reactivity
10.1 Reactivity
100 mg/cu m (as Cu) Copper dusts and mists
Mixtures with acetylenic compounds, ethylene oxide and azides are shock-sensitive. Reacts with strong oxidants such as chlorates, bromates and iodates strong oxidants such as chlorates, bromates and iodates. This generates explosion hazard.
10.2 Chemical stability
Becomes dull when exposed to air. in moist air gradually becomes coated with green basic carbonate.
10.3 Possibility of hazardous reactions
COPPER combines violently with chlorine trifluoride in the presence of carbon [Mellor 2, Supp. 1, 1956]. Is oxidized by sodium peroxide with incandescence [Mellor 2:490-93, 1946-1947]. Forms an unstable acetylide when acetylene is passed over samples that have been heated enough to form an oxide coating. Reacts more rapidly in powdered or granular form. Subject to explosive reaction then mixed in finely divided form with finely divided bromates chlorates and iodates of barium, calcium, magnesium, potassium, sodium, or zinc; these reactions are initiated by heat, percussion, and occasionally light friction [Mellor 2:310, 1946-1947]. A solution of sodium azide in copper pipe with lead joints formed copper azide and lead azide, both of these compounds can detonate [Klotz, 1973].
10.4 Conditions to avoid
no data available
10.5 Incompatible materials
Reacts violently with ... ammonium nitrate, bromates, chlorates, iodates, chloride, ... ethylene oxide, ... hydrazine mononitrate, hydrazoic acid, ... and potassium oxide .
10.6 Hazardous decomposition products
no data available
SECTION 11: Toxicological information
Acute toxicity
- Oral: LD50 - rat (male/female) - 300 - 500 mg/kg bw.
- Inhalation: LC50 - rat (male/female) - > 5.11 mg/L air.
- Dermal: LD50 - rat (male/female) - > 2 000 mg/kg bw.
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
Cancer Classification: Group D Not Classifiable as to Human Carcinogenicity
Reproductive toxicity
no data available
STOT-single exposure
Inhalation of fumes may cause metal fume fever. See Notes.
STOT-repeated exposure
Repeated or prolonged contact may cause skin sensitization. Ingestion may cause effects on the liver.
Aspiration hazard
A harmful concentration of airborne particles can be reached quickly when dispersed.
SECTION 12: Ecological information
12.1 Toxicity
- Toxicity to fish: LC50 - Pimephales promelas - 193 μg/L - 96 h.
- Toxicity to daphnia and other aquatic invertebrates: These observations consistently show that the presence of organic matter decreases the bioavailability, uptake, and ecotoxicity of copper in the aquatic environment - Daphnia magna.
- Toxicity to algae: Based on the algal biomass, the growth rate, the pigment diversity and the autotrophic index, an optimal concentration range was observed between 1 and 35μg Cu/L. - Pseudokirchneriella subcapitata (previous names: Raphidocelis subcapitata, Selenastrum capricornutum).
- Toxicity to microorganisms: see summary - activated sludge of a predominantly domestic sewage.
12.2 Persistence and degradability
no data available
12.3 Bioaccumulative potential
no data available
12.4 Mobility in soil
no data available
12.5 Other adverse effects
no data available
SECTION 13: Disposal considerations
13.1 Disposal methods
Product
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
SECTION 14: Transport information
14.1 UN Number
| ADR/RID: UN3089 (For reference only, please check.) | IMDG: UN3089 (For reference only, please check.) | IATA: UN3089 (For reference only, please check.) |
14.2 UN Proper Shipping Name
| ADR/RID: METAL POWDER, FLAMMABLE, N.O.S. (For reference only, please check.) | IMDG: METAL POWDER, FLAMMABLE, N.O.S. (For reference only, please check.) | IATA: METAL POWDER, FLAMMABLE, N.O.S. (For reference only, please check.) |
14.3 Transport hazard class(es)
| ADR/RID: 4.1 (For reference only, please check.) | IMDG: 4.1 (For reference only, please check.) | IATA: 4.1 (For reference only, please check.) |
14.4 Packing group, if applicable
| ADR/RID: II (For reference only, please check.) | IMDG: II (For reference only, please check.) | IATA: II (For reference only, please check.) |
14.5 Environmental hazards
| ADR/RID: No | IMDG: No | IATA: No |
14.6 Special precautions for user
no data available
14.7 Transport in bulk according to IMO instruments
no data available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations specific for the product in question
| Chemical name | Common names and synonyms | CAS number | EC number |
|---|---|---|---|
| Copper | Copper | 7440-50-8 | 231-159-6 |
| European Inventory of Existing Commercial Chemical Substances (EINECS) | Listed. | ||
| EC Inventory | Listed. | ||
| United States Toxic Substances Control Act (TSCA) Inventory | Listed. | ||
| China Catalog of Hazardous chemicals 2015 | Not Listed. | ||
| New Zealand Inventory of Chemicals (NZIoC) | Listed. | ||
| Philippines Inventory of Chemicals and Chemical Substances (PICCS) | Listed. | ||
| Vietnam National Chemical Inventory | Listed. | ||
| Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) | Listed. | ||
| Korea Existing Chemicals List (KECL) | Listed. | ||
SECTION 16: Other information
Information on revision
| Creation Date | July 15, 2019 |
|---|---|
| Revision Date | July 15, 2019 |
Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
- HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
- CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
- Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
- ECHA - European Chemicals Agency, website: https://echa.europa.eu/
Other Information
The symptoms of metal fume fever do not become manifest until a few hours have passed.UN 3089 refers to METAL POWDERS, FLAMMABLE, (n.o.s.)
Any questions regarding this SDS, Please send your inquiry to sds@xixisys.com
Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.